Thermal kinetics, thermodynamics, decomposition mechanism, and thermal safety performance of typical ammonium perchlorate-based molecular perovskite energetic materials

Kinetics of Thermal Decomposition of Cubic Ammonium Perchlorate

The methods of thermogravimetric analysis (TGA) and differential scanning calorimettry (DSC) have been used to study the thermal decomposition of ammonium perchlorate (AP). TGA curves obtained under both isothermal and nonisothermal conditions show a characteristic slowdown at the extents of conversion, R ) 0.30-0.35. DSC demonstrates that in this region the process changes from an exothermic t...

The Role of Boron in Thermal Decomposition of Ammonium Perchlorate

Simultaneous thermal analysis (STA) method has been applied to study decomposition reactions of AP under a flowing nitrogen atmosphere and static air. Results obtained indicate that a phase transformation occurs prior to the decomposition reaction. Decomposition takes place exothermally in two stages, first stage of decomposition could be suppressed by the controlled heating programme. Addi...

the role of boron in thermal decomposition of ammonium perchlorate

simultaneous thermal analysis (sta) method has been applied to study decomposition reactions of ap under a flowing nitrogen atmosphere and static air. results obtained indicate that a phase transformation occurs prior to the decomposition reaction. decomposition takes place exothermally in two stages, first stage of decomposition could be suppressed by the controlled heating programme. addition...

The Thermal Decomposition of Ammonium Perchlorate : a ' Literature Review

Combustion Mechanism and Kinetics of Thermal Decomposition of Ammonium Chlorate and Nitrite

Combustion data of ammonium chlorate and nitrite have been analyzed. The leading reactions of combustion of both NH4ClO3 and NH4NO2 at low pressures have been shown to proceed in the condensed phase, with the burning rate defined by the decomposition kinetics at the surface temperature. The kinetics of NH4ClO3 and NH4NO2 decomposition have been calculated by using a condensed-phase combustion m...